A Sustainable Process for the Recovery of Valuable Metals from Spent Lithium Ion Batteries by Deep Eutectic Solvents Leaching

نویسندگان

چکیده

The feasibility of using low-environmental-impact leaching media to recover valuable metals from lithium ion batteries (LIBs) has been evaluated. Several deep eutectic solvents (DES) were tested as agents in the presence different type additives (i.e., H2O2). optimization Co recovery was carried out by investigating various operating conditions, such reaction time, temperature, solid (black mass) liquid ratio, additive type, and concentration. Leaching with final selected DES choline chloride (33%), lactic acid (53%), citric (13%) at 55 °C achieved an extraction yield more than 95% for cobalt. mechanism likely begins dissolution active material black mass (BM) followed chelation Co(II) DES. results obtained confirm that those are eco-friendly alternative strong inorganic acids used nowadays.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Leaching Process for the Recovery of Valuable Metals from Spent Lithium- Nickel-cobalt-manganese-oxide-based Lithium-ion Batteries

This study focused on the leaching process for the recycling of Li, Ni, Co, and Mn from the LiNixCoyMnzO2 (NCM) cathodes of spent lithium-ion batteries (LIBs). Eh–pH diagrams were used to analyze suitable leaching conditions. Operating variables, such as the concentration of H2SO4 (0.5–2.5 M), concentration of H2O2 (0–1 vol%), temperature (10–50 °C), stirring speed (400–800 rpm), and solid/liqu...

متن کامل

Recovery of cobalt sulfate from spent lithium ion batteries by reductive leaching and solvent extraction with Cyanex-272

Cobalt sulfate was recovered from crushed and screened prismatic type spent lithium ion batteries (LIBs) containing 5~20 % Co, 5~7 % Li, 5~10 % Ni, 15% organic chemicals, and 7% plastics together with Cu, Al, Fe, and Mn. Cobalt was reductively leached from the -16 mesh fraction in 1 h by stirring with 2 M H2SO4 and 6 vol% H2O2, at 60 C and 300 rpm using a solid/liquid ratio of 100 g/L to give a...

متن کامل

METALS RECOVERY FROM SPENT Zn-MnO2 BATTERIES BY HYDROMETALLURGY

A hydrometallurgical process for recycling spent Zn-MnO2 batteries was developed, involving leaching with sulfuric acid, purification by precipitation and metals separation for further recovery. Leaching of zinc oxide was easily attained while for manganese oxide was rather difficult depending on temperature and acid concentration. At 90oC and with the liquid/solid ratio of 20 L/kg, more than 9...

متن کامل

A New Thermal Process for the Recovery of Metals from Zinc-carbon and Alkaline Spent Batteries

The aim of this study is the thermal recovery of manganese and zinc from a mixture of zinc-carbon and alkaline spent batteries containing 40.9% of Mn and 30.1% of Zn after a preliminary physical treatment. Separation of the metals is carried out on the basis of their different phase change temperatures, the boiling point of zinc being 906°C and 1564°C that of Mn3O4, the main Mn-bearing phase in...

متن کامل

Microbial Leaching Process to Recover Valuable Metals from Spent Petroleum Catalyst Using Iron Oxidizing Bacteria

Spent petroleum catalyst from Korean petrochemical industry contains trace amount of metals such as Ni, V and Mo. Therefore an attempt was made to recover those trace metal using bioleaching process. Different leaching parameters such as Fe(II) concentration, pulp density, pH, temperature and particle size of spent catalyst particle were studied to evaluate their effects on the leaching efficie...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Materials proceedings

سال: 2022

ISSN: ['2673-4605']

DOI: https://doi.org/10.3390/materproc2021005100